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Natural Gas Thermodynamics Worked Example Reservoir Engineering Material Balance p/Z OGIP

Worked Example: Estimating Gas Reservoir OGIP & Reserves using p/Z Material Balance

Step-by-step petroleum reservoir engineering calculation estimating Original Gas In Place (OGIP), recoverable reserves, recovery factor, and drive mechanism diagnostics using linear p/Z regression.

Published
October 17, 2026
Reading Time
~6 Minutes
Technical Review
Process Design Engineer (B.Tech Chemical Engineering, 5+ Yrs Experience)
📑 Table of Contents (Tap to view sections)

    The general material balance equation (MBE) is one of the most powerful diagnostic and reserves evaluation tools available to the petroleum reservoir engineer. For a dry gas reservoir under volumetric pressure depletion, the relationship between reservoir pressure, gas compressibility, and cumulative production forms a fundamental straight line when plotted as $p/Z$ versus $G_p$.

    This worked example walks through the complete reservoir engineering analysis of a volumetric gas reservoir located at a true vertical depth of $9,500\text{ ft}$, evaluating dynamic Original Gas In Place ($G$), recoverable reserves ($EUR$), recovery factor ($RF$), and drive mechanism verification across five static pressure surveys.


    1. Reservoir Parameters & Production History

    Reservoir & Fluid Properties:

    • Initial Static Bottomhole Pressure ($p_i$): $250.0\text{ barg}$ ($3,640.7\text{ psia} = 251.01\text{ bar(a)}$)
    • Reservoir Temperature ($T_{res}$): $85.0^\circ\text{C}$ ($185.0^\circ\text{F} = 644.67\text{ R}$)
    • Gas Specific Gravity ($\gamma_g$): $0.65$ ($\text{Air} = 1.0$)
    • Economic Abandonment Pressure ($p_{ab}$): $25.0\text{ barg}$ ($377.3\text{ psia}$)

    Historical Static Bottomhole Pressure (BHP) Surveys:

    Production surveillance has recorded five high-accuracy shut-in pressure surveys over a 6-year production history:

    Survey Point Cumulative Gas $G_p$ (MMSCF) Measured BHP $P$ (barg) Measured BHP $P$ (psia)
    Point 1 (Initial) $0.0$ $250.0$ $3,640.7$
    Point 2 $2,500.0$ $225.0$ $3,278.1$
    Point 3 $5,000.0$ $200.0$ $2,915.5$
    Point 4 $7,500.0$ $175.0$ $2,552.9$
    Point 5 (Current) $10,000.0$ $150.0$ $2,190.3$

    2. Step 1: Real Gas Compressibility Factor ($Z$) & $p/Z$ Evaluation

    The gas deviation factor $Z(p, T)$ is computed at each survey point using the pseudo-critical properties of Standing and the Hall-Yarborough / Dranchuk-Abu-Kassem equation of state:

    For $\gamma_g = 0.65$: * $P_{pc} = 670.0 - 15.0 \cdot (0.65 - 0.55) = 668.5\text{ psia}$ * $T_{pc} = 168.0 + 325.0 \cdot (0.65 - 0.55) = 200.5\text{ K} = 360.9\text{ R}$ * Pseudo-reduced temperature: $T_{pr} = \frac{644.67}{360.9} = 1.786$

    Point-by-Point $p/Z$ Computation:

    1. Initial Survey ($p_i = 3,640.7\text{ psia}$):
    2. $P_{pr,i} = \frac{3,640.7}{668.5} = 5.446$
    3. $Z_i = \mathbf{0.8543}$
    4. $(p/Z)_i = \frac{3,640.7}{0.8543} = \mathbf{4,261.6\text{ psia}} \quad (\mathbf{293.8\text{ bar}})$

    5. Survey 2 ($p = 3,278.1\text{ psia}, G_p = 2,500\text{ MMSCF}$):

    6. $P_{pr} = 4.904 \rightarrow Z = \mathbf{0.8581}$
    7. $p/Z = \frac{3,278.1}{0.8581} = \mathbf{3,819.5\text{ psia}} \quad (\mathbf{263.3\text{ bar}})$

    8. Survey 3 ($p = 2,915.5\text{ psia}, G_p = 5,000\text{ MMSCF}$):

    9. $P_{pr} = 4.361 \rightarrow Z = \mathbf{0.8642}$
    10. $p/Z = \frac{2,915.5}{0.8642} = \mathbf{3,374.0\text{ psia}} \quad (\mathbf{232.6\text{ bar}})$

    11. Survey 4 ($p = 2,552.9\text{ psia}, G_p = 7,500\text{ MMSCF}$):

    12. $P_{pr} = 3.819 \rightarrow Z = \mathbf{0.8728}$
    13. $p/Z = \frac{2,552.9}{0.8728} = \mathbf{2,924.9\text{ psia}} \quad (\mathbf{201.7\text{ bar}})$

    14. Survey 5 ($p = 2,190.3\text{ psia}, G_p = 10,000\text{ MMSCF}$):

    15. $P_{pr} = 3.276 \rightarrow Z = \mathbf{0.8842}$
    16. $p/Z = \frac{2,190.3}{0.8842} = \mathbf{2,477.1\text{ psia}} \quad (\mathbf{170.8\text{ bar}})$

    3. Step 2: Linear Regression Analysis ($p/Z$ vs $G_p$)

    Under the classical Craft & Hawkins material balance relation:

    Applying least-squares linear regression to the five coordinates $(G_p, p/Z)$:

    • Slope ($m$): Or in oilfield units: $\mathbf{-178.45\text{ psia/BCF}}$

    • Intercept ($p_i / Z_i$):

    • Coefficient of Determination ($R^2$):


    4. Step 3: Original Gas In Place (OGIP $G$) Determination

    In a volumetric gas reservoir, extrapolating the linear regression line to $p/Z = 0$ yields the Original Gas In Place ($G$):


    5. Step 4: Abandonment Pressure & Recoverable Reserves ($EUR$)

    At field abandonment pressure $p_{ab} = 25.0\text{ barg}$ ($377.3\text{ psia}$): * $P_{pr,ab} = \frac{377.3}{668.5} = 0.564 \rightarrow Z_{ab} = \mathbf{0.9702}$ * $(p/Z)_{ab} = \frac{377.3}{0.9702} = \mathbf{388.9\text{ psia}} \quad (\mathbf{26.8\text{ bar}})$

    Estimated Ultimate Recovery ($EUR$):

    Field Recovery Factor ($RF$):

    Remaining Recoverable Reserves:

    Given current cumulative production of $G_p = 10,000.0\text{ MMSCF}$ ($10.00\text{ BCF}$):


    6. Step 5: Drive Mechanism Diagnostics (Cole & Havlena-Odeh Plots)

    To confirm whether active water drive or aquifer influx is present, the reservoir expansion terms are calculated:

    Evaluating the Cole diagnostic grouping $F / E_g$ across historical points: * Underground voidage $F = G_p B_g$ * Gas expansion $E_g = B_g - B_{gi}$

    Because $R^2 = 0.9998$ and the residuals show zero upward curvature ($residuals[-1] \approx 0$), the Havlena-Odeh plot of $F$ vs $E_g$ forms a straight line passing through the origin with slope $G = 23.88\text{ BCF}$. This positively confirms a 100% Volumetric Depletion Drive with zero active aquifer water support.


    7. Engineering Summary & Results Dashboard

    Parameter Oilfield Units Metric Units Engineering Assessment
    Original Gas In Place ($G$) $\mathbf{23.88\text{ BCF}}$ $676.2\text{ MSm}^3$ Connected dynamic reservoir gas volume
    Estimated Ultimate Recovery ($EUR$) $\mathbf{21.70\text{ BCF}}$ $614.5\text{ MSm}^3$ At economic $p_{ab} = 25\text{ barg}$
    Current Cumulative Production ($G_p$) $\mathbf{10.00\text{ BCF}}$ $283.2\text{ MSm}^3$ $41.87\%$ of OGIP produced to date
    Remaining Recoverable Reserves $\mathbf{11.70\text{ BCF}}$ $331.3\text{ MSm}^3$ Backlog available for contractual delivery
    Field Recovery Factor ($RF$) $\mathbf{90.87\%}$ $90.87\%$ Exemplary recovery for volumetric gas
    Regression Correlation ($R^2$) $\mathbf{0.9998}$ $0.9998$ Confirms classic tank depletion
    Drive Mechanism Diagnostic Volumetric Depletion Closed Tank Zero water influx detected
    
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    References

    • Craft, B.C., Hawkins, M., and Terry, R.E. - Applied Petroleum Reservoir Engineering (3rd Edition, Prentice Hall, 2014) - Book
    • Havlena, D. and Odeh, A.S. - The Material Balance Equation with Linear Programming (Journal of Petroleum Technology, SPE-559-PA, 1963) - Paper [Link ↗]
    • SPE Petroleum Engineering Handbook, Volume V: Reservoir Engineering (Society of Petroleum Engineers, 2007) - Book [Link ↗]
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    Engineering Standards & Peer-Review Governance

    Authored & Verified by Process Design Engineer (B.Tech Chemical Engineering, 5+ Yrs Experience)

    Reservoir material balance calculations adhere to classical Craft & Hawkins and Havlena-Odeh straight-line formulations. Real gas compressibility factors Z(p,T) are evaluated via Dranchuk-Abu-Kassem and Hall-Yarborough equations of state.

    Domain Thermodynamics
    Governing Standards SPE Petroleum Engineering Handbook Vol. V, Craft & Hawkins Applied Petroleum Reservoir Engineering, Havlena-Odeh (1963)
    Content Classification Worked Example
    Verification ✓ Benchmark Validated
    Cite this technical guide:
    ChemProCal Engineering (2026). "Worked Example: Estimating Gas Reservoir OGIP & Reserves using p/Z Material Balance." ChemProCal Engineering Fundamentals. https://www.chemprocal.com/blog/worked-example-gas-reservoir-material-balance-pz-reserves/